• AWWA ACE65182
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AWWA ACE65182

  • Considering Water Quality Impacts During Chlorine Alternative Evaluations
  • Conference Proceeding by American Water Works Association, 06/01/2007
  • Publisher: AWWA

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This poster paper presents an effort bt the Medford Water Commission (MWC) to evaluate alternatives to chlorine gas disinfection systems at the Robert A. Duff Water Treatment Plant (Duff WTP) and the big Butte Springs Facility (BBS).The primary alternative examined was sodium hypochlorite,either as a 12% bulk solution or 0.8% solutiongenerated from salt. Hypochlorite raises the pH of thewater and could potentially affect the optimum dose ofpolyaluminum chloride (PACl) for turbidity removal.The Duff WTP is not currently operated in an "enhanced"coagulation mode for total organic carbon (TOC) removal. The diurnal pHchange and its impact on the coagulation system werealso considered, since alum is more sensitive to pHchanges than PACl.Bench scale experiments were conducted on June 15 - 17, 2005 toinvestigate the water quality impacts resulting from sodium hypochloriteuse instead of chlorine gas at the Duff WTP and BBS. The bench-scaleresults verified results from the Rothberg, Tamburini & Windsor (RTW)computer model. Additional testing was also conducted on August 19, 2005.Testing included pH adjustment as a function of sodium hypochloriteand coagulant addition, bromate testing of on-site generated and bulksodium hypochlorite, and pH control using carbon dioxide to create afavorable coagulation system. Simulated Distribution System (SDS)tests were performed to evaluate the disinfection byproduct (DBP)formation at different pH values, and an evaluation of the contact time(CT) requirements at various pH values and the impact of the pHchanges on the distribution system were also evaluated. Bench scale testing goals are listed, and figures charting the pH response to sodium hypochlorite are provided. Includes table, figures.

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